• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    1410644 Thiophosphate esters CIBAGEIGY AG 29 Sept 1972 [30 Sept 1971 27 July 1972] 24129/75 Divided out of 1410643 Heading C2P The invention comprises compounds of the general formula wherein R 1 is methyl or ethyl, R 2 is C 3 -C 5 alkyl, R 3 is C 1 -C 4 alkylcarbonyl or C 1 -C 4 - alkoxycarbonyl, R 4 and R 5 independently are H or a halogen atom and X is O or S, but excluding the compounds numbered 32 to 36 inclusive, 72, 73, 74, 88 and 89 disclosed in Specification No. 1,345,629 as originally published. They may be obtained by the following methods wherein Me is an alkali metal or an ammonium or alkylammonium group. The products have insecticidal, acaricidal and nematicidal properties and may be used as active ingredients in conventional pesticidal compositions.
    公开号:SU713525A3
    申请号:SU721835802
    申请日:1972-09-29
    公开日:1980-01-30
    发明作者:Драбек Йосеф；Варсаний Денис
    申请人:Циба-Гейги Аг (Фирма)；
    IPC主号:
    专利说明:

    (54) INSECTICIDE MEANS
    1 1:; () 6pCTciiiiL refers to means of combating rsd1pe., Namely to an insecticidal agent on the basis of 0-С |) enp, () ;; s. Ufpror, D11 Alknltnof () of the relevant Kn. yut. Compounds of formulas are known, where R is up to 2 This target is available; 1: asthma using sredsggg. content / c ;: And, eg (1 as ds11stvu Compound form; 1s III ucxiyniioT interdependent and one hundred and eleventh day of sport i and i si 11 forms l s
    RiS (RoO) p (x) C1 with cooTHCTCTByioHtHM replacing HcHiibiM (with renol in the presence of SUBLICATED acid, or with fOH-UiM pheno; 1 then 1 times.chart temperature; e O-130C inertia |.
    I | ziestp-) With coc; i, iHCiiiic
    Example. Insecticidal disease: Spodoptera littoralis.
    The plants of Chloik O11p1 1 are discarded by vodioG emulsion with a 0.05% content of the source of my connection. After B1) 1 dry; emu.tatsin on {asthenia iomontspot .1peiki Spexies Spodoptera littoralis in stage Aj.
    four
    solids or solvents, possibly in the presence of catalysts, iairi.me. of copper or copper chloride.
    Compounds of the formula III, presented in the table (see p. 3), are obtained by such methods.
    Res Mvtay IsipiiG.
    For one I am: about the United States of America. Ib.j.yyoT 110 two planes (mn1 and rezu; 1ttat1 1 deiictvi nodschnt1n a1 from 2, 4. 8, 24 and 48 h. Oyyt spend nri and (i ()% - Hoii o iTiociiTe.Tbiioii v.ta /; iostn with j3 spirit.
    For comparison, they apply and:; 15stios is connected and e-0,0-d PATH; - 0- / g-carb-yy () csnfeni .lOBbiii ether Tiio () () e (i) Oj: iiioii kslo1Bi. Formula nzooretspi Iskktitsplny means containing OfsskHKTOPYS Efpr Dyskltklt1; OfOsf (). X sour. As act1Chm1; () Ill with with the fact that, e tse.chyo povpenp 1: sectpipp () n actppopoetp. Oyu der / K1: t in ka. sspn O-fymm.tovykh firov dpa. cplti () phosphorus1: c: x kepelot essdshich f () rmu | 1; ,, R olpi from Kz, Ri n RS - acetyl, (i - Cb-a / iKjKciicarbonH .i. Amhka arbonp ;, revenge; 1a.1111karbocil, I M1fluorst; 1L, and osta.-1y; oyh- (1L- megapl, lo): x, -., - ,,,,, -. ,, ,, ,, - ,, -, n 1 l .-- cllesorol, cipa, and ivi), | 1Ч (, 11 ve UI - 95%. IjiilOpirreT; 1 :) IlpilJIianaM: 30.09.71 p |) n Ivi - a. C, - R --met ;; l, eptl; od:;: pz (:;, R., R-; - acetyl.Ci - C; ja.TKOKSpk; 1rb (), m;,:. a.ViiinoKa) 6 () iii.;, methi .tampo a1 b ;; l: .1, tr; 1 (rto | 1g; from tl:;, and L15a ogtal1 ji.,: military ch. h.yur: 1: 1.07.72 two;:; R: ,, -1 and R ;, blink: p:; drew; atv,;,: ei n.; a. 11tetoch; square iinibopMauiin, nominated 1; 0 iiii.iMainia prl - Ilt ii Shleiparpi L 500230, c. 01 X 9/30, (; publ. L. 29.01.71. 2. Scliiader G. Die RiitwiekiiHg r.eiier insekiizidcr Rhosphorsauresster, Maniilielm, (neinie, 1963, e. 250 (lrotopp).
    权利要求:
    Claims (1)
    [1]
    The formula is invented. I Insecticidal agent containing 0 phenyl ethers of dicalcitophosphoric acids as an active substance and an additive selected from the troupe: carrier, solvents, dispersant, wetting agent, thickener, 10 characterized in that, in order to increase insecticidal activity, it contains O- fsp of the dialklthiophosphoric acid dialkyl esters of the compound of formula 3, one of R 3 , R. t and R s is acetyl. C; —C 3 -alkoxy-carboncarbonyl, aminocarbonyl, mstinamniocarbonyl, trifluoro;, —style, and the other two — hydrogen, methyl, chlorine:
    IΙηποριιτοτ on the grounds of:
    09/30/71 at R t - alkyl C ;; - C 5 ; R <...... revenge, ethyl;
    one of R 3 , R ( and Rs is acetyl, Cj is C 3 -alkox I! to arbos! ..!. aminocarb ™ sh, avenged aminoschbonyl, τρ and fluorine avenged, and two remaining hydrogen, chlorine:
    07/21/72 npya methyl.
    类似技术:
    公开号 | 公开日 | 专利标题
    SU713525A3|1980-01-30|Insecticidic composition
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    JPS63205394A|1988-08-24|Lubricating oil composition
    IT8023093D0|1980-06-26|PROCEDURE FOR THE PREPARATION OF LUBRICANT OIL COMPOSITIONS CONTAINING MOLYBDENUM COMPOUNDS AS ANTIOXIDANT ADDITIVES.
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    JPS6420A|1989-01-05|Organ-protecting agent
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    GB1313247A|1973-04-11|Thiono- phosphoric -phosphonic- acid esters a process for their preparation and their use as insecticides and acaricides
    ES8203820A1|1982-05-01|Cyclopropanecarboxylic acid alkynyl esters, processes for producing them, and their use as pesticides
    GB1376558A|1974-12-04|Quinoline-thionophosphonic acid esters a process for their preparation and their use as insecticides and acaricides
    同族专利:
    公开号 | 公开日
    JPS5314622B2|1978-05-18|
    GB1410643A|1975-10-22|
    GB1410644A|1975-10-22|
    NL7213235A|1973-04-03|
    FR2154745A1|1973-05-11|
    CA1048050A|1979-02-06|
    IT968467B|1974-03-20|
    IL48060D0|1975-11-25|
    US3839509A|1974-10-01|
    HU166376B|1975-03-28|
    CA1048046A|1979-02-06|
    DE2247268A1|1973-04-05|
    EG11510A|1977-11-30|
    IL40396A|1976-11-30|
    CS179390B2|1977-10-31|
    AT316213B|1974-06-25|
    JPS4840936A|1973-06-15|
    DD101542A5|1973-11-12|
    IL40396D0|1972-11-28|
    BE789439A|1973-03-29|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US4005197A|1972-04-06|1977-01-25|Bayer Aktiengesellschaft|Combating insects, acarids and nematodes with S-alkoxyethyl-phenyl-di- and tri-thiophosphonic acid esters|
    JPS5053532A|1973-09-21|1975-05-12|
    US4008319A|1974-12-12|1977-02-15|Rohm And Haas Company|O,S-dialkyl O-benzoyl-phenyl phosphorothiolates and phosphorodithioates, pesticidal compositions and methods of use|
    JPS5926634B2|1976-07-27|1984-06-29|Nihon Tokushu Noyaku Seizo Kk|
    US4299772A|1980-03-04|1981-11-10|Velsicol Chemical Corporation|Xanthenone-yl esters of phosphoric and phosphonic acids|
    US4404220A|1980-03-04|1983-09-13|Velsicol Chemical Corporation|Xanthenone-yl esters of phosphoric and phosphonic acids|
    DE3037414A1|1980-10-03|1982-05-19|Basf Ag, 6700 Ludwigshafen|4-TRIFLUORMETHYLPHENYL-THIOPHOSPHORIC ACID ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR CONTROLLING Pests|
    DE3201227A1|1982-01-16|1983-07-28|Basf Ag, 6700 Ludwigshafen|2-TRIFLUORMETHYLPHENYL--THIOPHOSPHORIC ACID ESTER, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR CONTROLLING Pests|
    US4436736A|1982-03-29|1984-03-13|Union Carbide Corporation|Methods for controlling pests with substituted phenyl thiophosphates and the thiophosphates|
    US4736053A|1986-01-22|1988-04-05|Otsuka Kagaku Kabushiki Kaisha|Phosphoric ester derivatives and insecticidal and miticidal compositions containing said derivatives|
    DE3732527A1|1987-09-26|1989-04-06|Basf Ag|O--O-BORDER CATALINE DERIVATIVES|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    CH1420871A|CH564307A5|1971-09-30|1971-09-30|Subst phenylthiophosphates - wi h pesticidal activity|
    CH1122972|1972-07-27|
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